Rare Unlockables

You can scan the following Amiibo figurines once per day in the hope of getting it's rare items which it drops randomly. The tunics are 3-part armour sets that consist of cap, tunic, and leggings. Some items like Epona will only appear when you have the Paraglider or after completing one Divine Beast dungeon. Note: Epona is guaranteed to drop the first time you scan Super Mario Bros Link and then randomly thereafter if she is lost. As you can only get Epona once per save game to keep her permanently you should wait until you have a stable before you summon her.

Biggorron's Sword:

30th Anniversary Ocarina of Time Link

Epona:

Super Smash Bros Link

Hero's Shield:

30th Anniversary Wind Waker Zelda

Sea-Breeze Boomerang:

30th Anniversary Wind Waker Link or Super Smash Bros Toon Link

Sheik's Mask:

Super Smash Bros Sheik

Sword:

30th Anniversary 8-bit Link

Sword of the Six Sages:

Super Smash Bros Ganondorf

Traveler's Saddle and Bridle:

Breath of the Wild Rider Link

Tunic of the Hero (Armour Set):

30th Anniversary 8-bit Link

Tunic of the Wind (Armour Set):

30th Anniversary Wind Waker Link or Super Smash Bros Toon Link

Tunic of Time (Armour Set):

30th Anniversary Ocarina of Time Link

Tunic of Twilight (Armour Set):

Super Smash Bros Link (2nd Time and Beyond)

Twilight Bow:

Super Smash Bros Zelda