Two questions.
1. When does Charizard learn Fire Blast?
2. Does Pickachu learn any moves after level 66?
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Charizard must learn Fire Blast using a TM. Pikachu cannot learn anything past level 66, so now's a good time to evolve it.
1.Charizard can't learn Fire Blast by leveling up.
2.No,Pikachu does not.
Charizard learns fireblast from the tm only and pickachu does not learn any moves after level 66.
Charizard learns Fire Blast with a TM. And Pikachu doesn't learn any moves after level 66. So you should evolve it into Raichu with a Thunderstone now.
-Raichu is also very, very fast, so get him NOW.
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