Firstly how do you get Alexander?
Also, the only way to get Ark is to either defeat Hades and give him 2 pumice pieces(one of which you get after you beat ark, the other from a chocograph Outer Island 2, which is the Island just below Mognet Central(on the top of the map, to the East).
When you have these 2 Pumice Pieces you can give them to Hades and he will synthesise them into a Pumice.
The other is getting it from Ozma.
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