How do you get a Master Ball?
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You get the Master Ball from the Team Aqua Hideout B3F. The Master Ball can be used for catching wild Pokemon.
If you are still looking for help with this game we have more questions and answers for you to check.
In the Team Aqua Hideout. The exact room where it's located happens to be Archie's room. If you miss it the first time (when trying to reach the submarine), you'll end up coming back during the Delta Episode when Zinnia pays a visit, as she'll be confronting Matt and Shelly there.
In Pokemon red, you beat up team rocket at silph co., then you talk to the silph co. Presedent and he
Will give you a master ball as thanks for saving him.