Invincible, Invisible, and ammo
Simple profile editing is involved for this cheat.
First, start a new game and create a new profile and save it. Exit the game and go to the profiles folder in this path. My Computer ; C: ; Documents and Settings ; All Users ; Application Data ; Ubisoft ; Tom Clancy's Splinter Cell Chaos Theory ; Profiles ; then whatever profile you choose. Remember, Application Data is a hidden file, so you will have to set folders up to view hidden files.
Now open the profile configuration settings for the profile you created with just about any word program. Move down to the F key assignments and find three of them that are unassigned. Write them down on a piece of paper or remember what you attach to each key. F2, F3, and F4 should be open. Here the example of what you will see when you're done.
F2=invisible
F3=invincible
F4=ammo
Save your changes and close the window and play the game with that profile.
Hitting the hotkey on invisible and invincible will toggle it on and off each time you hit it. You will have to engage the cheats for each mission after it starts.
Have Fun.
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