I've Seen People use a Poke Modifier to Catch level 100 pokes. If you have to catch the Pokemon than how you use the modifier for level 100's???
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If it's the code I think you're talking about, try holding L as you go into a wild battle. If that doesn't work, try holding Select instead.
You imput the code into an Action Replay and run it off of that. Visit the AR forum for more details.
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