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Between battles you can upgrade Captain America and the agents by spending credits or synthesizing blends of ISO-8.
Use the special Avengers tokens to summon Falcon and Black Widow when you find yourself being overwealmed by the enemy as thesse characters will help you eliminate them.
Make yourself a hard target to hit by constantly moving.
Use the environment to your advantage by looking for items that can be exploded to get free kills.
You can score an easy hit by starting each of your attacks with a shield-throw to take out the shield bearers.