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When you have a 100% game completion by finishing ALL 40 lessons, the free paintings, and the quick draw lessons you will gain the Grand Master Card.
At the beginning of the game you can only play the Starter Exercises where you have the choice between Froakie, Piplup, or Pikachu. When you manage to beat one of them you will be accepted at Pokemon Art Academy where you will begin the different courses.
Apprentice Course:
Beat Novice Test.
Bonus Lessons:
Beat Graduate Test.
Graduate Course:
Beat Apprentice Test.
Novice Course:
Beat one of the Starter Exercises.