Where do you fine pichu and at what level does it learn volt tackle?
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Pichu can be found at 3-6F of Joyous Tower
It will learn Volt Tackle at Lv50 *WITH* 333 IQ (you have to feed it Gold Gummi)
You can learn it from Gulpin Shop if you have already pass Lv50.
Pichu can't learn volt tackle because it is a fourth generation move and you are playing a third generation game
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