How to get master balls on Pokemon diamond version.
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You can obtain one Masterball throughout the Game. You obtain it from a Team Galactic Commander at the end of Team Galactic's Building in Veilstone City.
You can also obtain Masterballs by Trade or by an AR Code.
Hope this helps!
The one and only masterball in diamond is the one that the boss of team galactic gives you.
Hope I helped
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