dusk balls
Dusk balls are probably the best balls after the master ball. Dusk balls work best at night or in a cave.so what I always do is wait till 8:00 pm or later and catch Pokemon with a dusk ball, which works even better than an ultra ball.
*NOTE*
Dusk balls are superb for catching the legendary pokemon. Wait till night and then you can catch dialga(i actually caught dialga with a pokeball. Sweet, huh?) and palkia, gratania, azelf and uxie (mesprit is a find and catch Pokemon so dusk balls are okay but not as effenctive, same with cresselia), heatran, regigigas, androtom.
Hope this helps
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