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These hidden characters become unlocked when you reach Level 5 and beat Cell using the indicated character as your 'Main Personality'. After the battle you will receive the character's Main Personality Level 1-3 cards inside the booster pack.
Unlock Krillin:
Beat Cell with Guldo as your Main Personality.
Unlock Trunks:
Beat Cell with Gohan as your Main Personality.
Unlock Guldo:
Beat Cell with Nail as your Main Personality.
Unlock King Cold:
Beat Cell with Frieza as your Main Personality.
Unlock Nail:
Beat Cell with Goku as your Main Personality.
Unlock Piccolo (both Heroes and Villain sides):
Beat Cell with Garlic Jr. As your Main Personality.
Unlock Vegeta (both Heroes and Villain sides):
Beat Cell with King Cold as your Main Personality.