Unlock Characters
This is done by clearing chapters, below is a list of the characters that can be unlocked and what chapter needs to be cleared to get them.
Unlock Shinji:
Clear Chapter 3
Unlock Yami:
Clear Chapter 6
Unlock Grimmjaw:
Clear Chapter 10
Unlock Noitora:
Clear Chapter 26
Unlock Aaroniero:
Clear Chapter 27
Unlock Ulquiorra:
Clear Chapter 29
Unlock Szayel:
Clear Chapter 32
Unlock Zomari:
Clear Chapter 36
Unlock Nel:
Clear Chapter 41
Unlock Ichimaru Gin:
Clear Chapter 47
Unlock Aizen:
Clear Chapter 49
We have more cheats and tips for this game here, Bleach: Versus Crusade cheats
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