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At the 'Character Select' screen keep the 'Start' button held down and highlight the characters in the following order and press X and O before releasing the 'Start' button.
1 - Haohmaru
2 - Ganjuro
3 - Basara
4 - Kyoshiro
5 - Ukyo
6 - Rimruru
7 - Haohmaru
8 - Shizmaru
9 - Nakoruru
10 - Hanzo
11 - Amakusa
12 - Gaira
13 - Galford
14 - Shizmaru