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When the games starts and you see the Prinny dancing at the 'Now Loading' screen you can make it explode by rapidly pressing R3 enough times before you reach the 'Main' menu.
Complete the indicated task to unlock the corresponding class.
Archer:
Get a Warrior or Valkyrie and a Priest or Cleric to level 15, and a Weapon Mastery with a Bow to at least level 5 or alternately unlock at the start of episode 5.
Armor Knight:
Get a Warrior or Valkyrie to level 20. With a Weapon Mastery with a Spear to at least level 7 or alternately unlock at start of episode 10
Beast Master:
Get a Warrior or Valkyrie to at least level 30. You must have used a Mounted Skill at some point.
Celestial Host Female:
Get a Cleric and an Onmyo Monk to at least level 100 or alternately clear episode 8.
Celestial Host Male:
Get a Priest and a Magic Knight to at least level 100 or alternately clear episode 8.
Gunner:
Get a Thief to level 15 or higher. One of your units must have raised their Weapon Mastery with a Gun to at least level 5.
Lady Samurai:
Get an Archer to level 30 or higher. One of your units must have raised their Weapon Mastery with a Sword to at least level 7.
Magic Knight:
Get a Warrior or Valkyrie and a Magician or Witch to at least level 20.
Masked Hero:
Get a Martial Artist or Fight Mistress to at least level 25.
Ninja:
Get a Thief and a Martial Artist or Fight Mistress to at least level 20.
Onmyo Monk:
Onmyo Monk: Get a Magician or Witch and a Priest or Cleric to level 10. Episode 2 must be cleared.
Shaman:
Get an Onmyo Monk to at least level 20.
Thief:
Get a Martial Artist or Fight Mistress to at least level 5.