Where can you get a second masterball not form the man in the black siut
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I am affraid there is no other way to get a 2nd masterball except for the man in black suit. Unless if you have an action replay for 900 masterballs.
You get a second masterball from Professor Juniper after getting all eight badges and head from Opelucid City to the Pokemon League.
Sorry but there is completely no other way to another master pokeball unless by action replay
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