Look I've got a Lv. 100 Riolu With max IQ how do I get him to evolve to Lucario
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You don't have to get his IQ'maxed. You have to up your friendship level with it. Then,make it go up a level (even if it's level 1 it will still evolve only if friendship is high). Now you have to get a different Riolu cause the one you have is already Lv.100 and can't evolve.
The IQ is nothing to do with evoultions nor is level. You need to build a high enough relationship with the Pokemon (in this case Riolu) and then make him/her level up once it (the relationship) is high enough. S/he should evolve then.
Good luck.
Riolu just needs a sun ribbon here's a code for one it's in an easy dungeon too (drenched bluff I think) H8C HF98 J5T+ F3@P =0YR PJC4
As for the friendship/IQ thing you're all wrong..
Pokemon that normally evolve on friendship in the diamond, pearl, platinum games evolve from a high IQ in Pokemon Mystery dungeon games.
For example:
Chingling - Chimecho
Eevee - Espeon/ Umbreon
Pichu- Pikachu
Munchlax- Snorlax
Riolu- Lucario
Buneary- Lopunny
Igglybuff- Jigglypuff
Golbat- Crobat
Happiny- Chansey
Azurill- Marill
Cleffa- Clafairy
You need the Sun Ribbon to get him to evolve. They're quite common in Gold Chamber Deluxe Boxes/
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