Whats the best Pokemon to catch in heartgold
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Probably any legendary Pokémon like entei or rakui or manye even ho-oh.
A Nidorino.
But seriously, "best" isn't a good word to use. There is no "best" Pokemon to catch.
Mewtwo can be seen as the ultimate prize. You can only catch Mewtwo by finding your way through the Cerulean Cave, which is only accessable after you get all of the badges. This makes Mewtwo one of the last Pokemon you are able to obtain in game. It is also one of the strongest (based on base stat totals).
Shiny Pokemon are extremely rare, and are often seen as very valuable. The only exception are shiny Gyarados, because everyone can find one at the Lake of Rage.
By logical extension, a shiny Mewtwo would be an amazing catch.
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