What do you do after you defeat all of the gym leaders?
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Explore the rest of the map. Complete your pokedex. Beat the Battle Subway. Make all of the movies at Pokewood. Beat that thing in Black City. Link up with a friend and do Funfest Missions. Visit the Dream World. Make it to the bottom of the Abyssal Ruins. Beat the Gamefreak Team in Castellia. There's more, I just don't feel like listing anymore.
After you have defeated the Eighth Gym Leader, you will have to go battle Team Plasma on Route 21. After you do this, the storyline will lead you to the Giant Chasm.
After you have defeated Team Plasma, Ghetsis, and Black Kyurem in Giant Chasm, the storyline will lead you to Victory Road. You will meet with N right after you get to Victory Road.
Go through Victory Road and then defeat the Elite Four. Once you have done this, you have finished the Main Storyline. You will then gain access to more locations in Unova.
Hope this helps!
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